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E.3.1 Stability and binding energy

Understanding Isotopes, Nuclear Stability, and the Strong Nuclear Force

  1. Imagine you're holding a helium balloon.
  2. The helium inside is made of atoms, and at the center of each atom lies a tiny nucleus containing protons and neutrons.
But here's a curious question: what keeps those positively charged protons from flying apart due to their mutual repulsion? And why do some nuclei stay stable for billions of years while others decay in seconds?

What Are Isotopes?

  • Every atom is defined by its number of protons, denoted as Z, which determines the element.

Example

For example, all carbon atoms have Z=6, meaning they each have 6 protons.

  • However, not all carbon atoms are identical—they can have different numbers of neutrons, N.
  • The total number of protons and neutrons, called the nucleon number, is denoted as A, where:

A=Z+N

  • Atoms of the same element with different numbers of neutrons are called isotopes. For example:
    • Carbon-12 (612C): 6 protons and 6 neutrons.
    • Carbon-14 (614C): 6 protons and 8 neutrons.

Key Properties of Isotopes

  • Same chemical properties: Since chemical behavior depends on the number of electrons, and isotopes have the same Z, their chemistry is identical.
  • Different physical properties: The difference in neutron number affects properties like mass and nuclear stability.

Example

Identifying Neutrons in an Isotope

Consider the isotope 1123Na.

  • Proton number (Z) = 11
  • Nucleon number (A) = 23
  • Neutron number (N) = AZ=2311=12

This sodium isotope has 12 neutrons.

Note

The existence of isotopes is direct evidence for the presence of neutrons in the nucleus, as A can vary while Z remains fixed.

Self review

How would you calculate the number of neutrons in the isotope 816O?

Binding Energy Per Nucleon: A Measure of Stability

  1. When you assemble protons and neutrons to form a nucleus, the total mass of the nucleus is slightly less than the sum of the individual masses of its protons and neutrons.
  2. This "missing mass" is called the mass defect, and it is converted into energy according to Einstein’s famous equation:

E=mc2

This energy, known as the binding energy, is what holds the nucleus together. The binding energy per nucleon is a key indicator of nuclear stability.
Definition

Binding energy

Binding energy is the energy required to hold the nucleus together.

Binding Energy per Nucleon=Total Binding EnergyNumber of Nucleons

The Binding Energy Curve

If we plot the binding energy per nucleon against the nucleon number A, we observe:

  1. Rapid increase for small nuclei: Light nuclei like helium (A=4) have relatively low binding energy per nucleon.
  2. Peak stability near iron (A60): Iron-56 has one of the highest binding energies per nucleon, making it extremely stable.
  3. Gradual decrease for heavier nuclei: As A increases beyond 60, the binding energy per nucleon decreases, making larger nuclei like uranium less stable.
Binding energy curve.
Binding energy curve.

Tip

The peak of the curve explains why energy is released in nuclear fusion (light nuclei combining) and nuclear fission (heavy nuclei splitting).

Analogy

Think of the nucleus as a tightly packed group of friends holding hands (the strong nuclear force). For small groups, everyone is connected. But as the group grows, some friends are too far apart to hold hands, and the group becomes harder to keep together.

Self review

Why does the binding energy per nucleon decrease for nuclei heavier than iron?

Mass-Energy Equivalence and Energy Release

  1. Einstein’s equation, E=mc2, reveals the deep connection between mass and energy.
  2. In nuclear reactions, mass is not conserved in the traditional sense—some of it is converted into energy.
  3. This is why nuclear reactions release such enormous amounts of energy compared to chemical reactions.

Energy from Mass Defect

The energy released in a nuclear reaction can be calculated using the mass defect (Δm):

Q=Δmc2

where:

  • Q is the energy released,
  • Δm is the difference in mass between the reactants and products,
  • c is the speed of light (3.00×108m/s).

Example

Energy Released in Alpha Decay

Consider the alpha decay of uranium-238:

92238U90234Th+24He

The masses are:

  • Uranium-238: 238.0508u
  • Thorium-234: 234.0436u
  • Helium-4: 4.0026u

Mass defect:

Δm=238.0508(234.0436+4.0026)=0.0046u

Energy released:

Q=Δmc2=0.0046931.5MeV/u=4.29MeV

Common Mistake

Many students forget to convert the mass defect into energy using the correct units (1 u = 931.5 MeV/c2).

The Strong Nuclear Force: The Glue of the Nucleus

Definition

The strong nuclear force

The strong nuclear force is one of the four fundamental forces of nature and is responsible for holding the nucleus together. It acts between all nucleons (protons and neutrons).

Key Characteristics

  1. Attractive and short-ranged: The strong nuclear force is incredibly strong at distances of 1015m (the size of a nucleus) but drops off rapidly beyond this range.
  2. Independent of charge: Unlike the electromagnetic force, the strong nuclear force acts equally between protons and neutrons.

Reflection and Applications

Self review

How does the range of the strong nuclear force compare to the range of the electromagnetic force?

Theory of Knowledge

How do we know the strong nuclear force exists? Consider the evidence:

  • Deviations from Rutherford scattering: High-energy alpha particles scatter differently than predicted by Coulomb’s law, indicating the presence of another force.
  • Nuclear stability: Without the strong nuclear force, nuclei with multiple protons would be impossible.

Understanding isotopes, binding energy, and the strong nuclear force is essential to explaining phenomena like nuclear stability, radioactive decay, and energy release in nuclear reactions.

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Questions

Recap questions

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Question 1

Consider the binding energy per nucleon for different isotopes of the same element. Which of the following statements is true?

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Note

Nuclear Stability and Forces

  • At the heart of every atom lies the nucleus, a tiny, dense core containing protons and neutrons.
  • Protons are positively charged, and like charges repel each other. This repulsive force is called electrostatic repulsion.
  • Despite this repulsion, nuclei don't just fly apart because another force, the strong nuclear force, holds them together.

Analogy

Think of the nucleus like a tightly packed ball of magnets, where the magnets naturally repel each other, but there's an invisible glue holding them together.

Example

Uranium-238, a naturally occurring element, has 92 protons packed into its nucleus. Without a stabilizing force, these protons would repel each other violently.

Note

The nucleus is about 100,000 times smaller than the atom itself, yet contains almost all of the atom's mass.