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S1.1.1 Elements, Compounds and Mixtures

Properties of Elements, Compounds, and Mixtures

Elements: The Building Blocks of Matter

Definition

Element

An element is the simplest form of matter that cannot be broken down into simpler substances by physical or chemical means.

Each element is made up of atoms, which are identical in their number of protons. Think of elements as the "purest ingredients" in chemistry.

Example

  • Hydrogen (H) is an element that exists as diatomic molecules (H2) in nature.
  • Iron (Fe) is an element found in the Earth's crust and is used to make steel.

Key Properties of Elements:

  • They consist of only one type of atom.
  • They are represented by chemical symbols (e.g., H for hydrogen, O for oxygen).
  • They cannot be physically or chemically split into simpler substances.

Tip

Use the periodic table to identify elements and their properties, such as atomic number and mass.

Periodic table.
Periodic table.

Compounds: Chemical Combinations of Elements

Definition

Compound

A compound is a substance formed when two or more different elements chemically bond together in fixed proportions.

Unlike mixtures, the components of a compound lose their individual properties and form a new substance with unique characteristics.

Example

  • Water (H2O) is a compound made of hydrogen and oxygen atoms in a 2:1 ratio. It has properties distinct from its constituent elements—hydrogen is explosive, and oxygen supports combustion, but water extinguishes fire.
  • Sodium chloride (NaCl), or table salt, is a compound formed by the bonding of sodium (a reactive metal) and chlorine (a toxic gas).

Key Properties of Compounds:

  • They have a fixed chemical formula (e.g., H2O, NaCl).
  • Their properties differ from the elements they are made of.
  • They can only be separated into their elements through chemical reactions.

Common Mistake

Don't confuse mixtures with compounds. A mixture of hydrogen and oxygen is not water—it’s just a mixture!

Mixtures: Physical Combinations of Substances

Definition

Mixture

A mixture contains two or more elements, compounds, or both that are physically combined but not chemically bonded.

  • Each component retains its original properties, and the composition can vary.
  • Mixtures can be classified into two types:
    1. Homogeneous mixtures: Uniform composition throughout (e.g., saltwater, air).
    2. Heterogeneous mixtures: Non-uniform composition (e.g., oil and water, sand and iron filings).

Key Properties of Mixtures:

  • Components are not chemically bonded.
  • They can be separated by physical methods (e.g., filtration, distillation).
  • The composition can vary (e.g., different concentrations of sugar in tea).

Note

Alloys, such as steel (iron and carbon), are mixtures, not compounds, because their components are not chemically bonded.

Pure Substances vs. Mixtures

Elements and Compounds as Pure Substances

Definition

Pure substance

A pure substance consists of only one type of particle with a fixed composition and uniform properties throughout.

  • Elements: Made of only one type of atom. Examples: oxygen (O2), iron (Fe).
  • Compounds: Made of two or more elements chemically bonded in a fixed ratio. Examples: water (H2O), sodium chloride (NaCl).

Compounds can only be separated into elements by chemical reactions, not physical methods.

Mixtures: Not Pure Substances

  • Homogeneous Mixtures: Uniform throughout (e.g., saltwater, air).
  • Heterogeneous Mixtures: Non-uniform with distinguishable components (e.g., sand and iron filings).

Separation Techniques: Isolating Components of Mixtures

Because mixtures are physically combined, their components can be separated using physical methods. Let’s explore some common techniques:

Filtration: Separating Solids from Liquids

Definition

Filtration

Filtration is used to separate insoluble solids from liquids. For example, sand can be separated from water using filter paper.

How it works:

  1. Pour the mixture through a funnel lined with filter paper.
  2. The liquid (filtrate) passes through, leaving the solid (residue) behind.

Example

Imagine you have a mixture of sand and water. After filtration, the sand remains on the filter paper, while the water collects in a container below.

Recrystallization: Purifying Solids

Definition

Recrystallization

Recrystallization exploits differences in solubility.

A soluble substance is dissolved in a hot solvent and then allowed to cool. As the solution cools, pure crystals form and can be separated.

Example

Purifying sugar from an impure sample by dissolving it in water, filtering out insoluble impurities, and then allowing the sugar to crystallize.

Tip

Use recrystallization when you need to purify a substance with slight impurities.

Evaporation and Distillation: Separating Based on Boiling Points

1.Evaporation:

Definition

Evaporation

Evaporation removes a liquid from a solution by heating it, leaving behind the dissolved solid.

Example

Salt can be obtained from saltwater by evaporating the water.

2.Distillation:

Definition

Distillation

Distillation separates two or more liquids with different boiling points.

The liquid with the lower boiling point evaporates first, is condensed, and collected.

Example

Separating ethanol (boiling point ~78°C) from water (boiling point ~100°C) using a distillation apparatus.

Distillation apparatus.
Distillation apparatus.

Paper Chromatography: Separating Mixtures of Solutes

Definition

Paper chromatography

Paper chromatography is a technique used to separate the components of a mixture based on differences in their solubility and polarity.

It works by allowing a solvent to move through chromatography paper, carrying the components of the mixture at different rates depending on how strongly they interact with the paper (stationary phase) and the solvent (mobile phase).

How It Works:

  1. A small drop of the mixture is placed near the bottom of a strip of chromatography paper.
  2. The paper is suspended in a solvent (like water or ethanol) with the spot above the solvent level.
  3. As the solvent moves upward by capillary action, it dissolves the solutes in the mixture.
  4. Components that are more soluble in the solvent travel further up the paper, while less soluble components stay closer to the starting point.

Example

Separating Pigments in Ink or Dyes:
A mixture of colored pigments can be separated using paper chromatography. For instance, black ink often separates into a range of colors like blue, red, and yellow as different pigments move at different speeds up the paper.

Key Factors Affecting Separation:

  • Polarity: Polar solutes dissolve better in polar solvents, while non-polar solutes dissolve better in non-polar solvents.
  • Solubility: Higher solubility in the solvent results in faster movement along the paper.
  • Molecular Size: Smaller molecules often travel faster than larger ones.

Tip

The ratio between the distance traveled by a solute and the solvent front is called the retention factor or Rf value, calculated as:

Rf=Distance traveled by soluteDistance traveled by solvent front

Rf values help identify substances by comparing them to known standards.

Common Mistake

Ensure the solvent level is below the initial spot on the paper to prevent the mixture from dissolving into the solvent directly.

Chromatography process.
Chromatography process.

Homogeneous vs. Heterogeneous Mixtures

Homogeneous Mixtures: Uniform Composition

In a homogeneous mixture, the particles are evenly distributed, and the composition is consistent throughout. Examples include:

  • Saltwater
  • Air (a mixture of nitrogen, oxygen, and trace gases)

Heterogeneous Mixtures: Non-Uniform Composition

In a heterogeneous mixture, the components are not evenly distributed. Examples include:

  • Oil and water (distinct layers form due to immiscibility)
  • Sand and iron filings

Analogy

Think of a homogeneous mixture as a well-blended smoothie, while a heterogeneous mixture is like a salad with distinct ingredients.

Illustration of heterogenous and homogenous mixtures.
Illustration of heterogenous and homogenous mixtures.

Applications and Implications

Understanding the properties of elements, compounds, and mixtures—and how to separate them—is crucial in fields ranging from environmental science to pharmaceuticals. For instance:

  • Water purification: Filtration and distillation are used to provide clean drinking water.
  • Food industry: Chromatography ensures the quality and safety of food additives.
  • Recycling: Separation techniques help recover valuable materials from waste.

Theory of Knowledge

Consider this: How does the ability to separate mixtures influence industries and economies? What ethical considerations arise when resources are unevenly distributed?

Reflection and Practice

Self review

  1. How does a compound differ from a mixture?
  2. What separation technique would you use to isolate salt from seawater?
  3. Can a mixture of hydrogen and oxygen be called water? Why or why not?

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Question 1

Which of the following statements best describes the difference between separating mixtures and separating compounds?

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Note

Matter and its Classification

Everything around us is made up of matter, and understanding its basic forms is fundamental to chemistry. Matter can be classified into three main categories: elements, compounds, and mixtures.

  • Elements are pure substances that consist of only one type of atom.
  • Compounds are substances formed when two or more elements chemically combine in fixed proportions.
  • Mixtures are physical combinations of substances that retain their individual properties.

Analogy

Think of elements as the letters of the alphabet, compounds as words formed by combining letters, and mixtures as sentences where words are simply placed together without changing their meaning.